Influence of Water Molecules on Properties of Binuclear or Bridged Structures for Chiral CuII-NiII, CuII-PdII, and CuII-PtIITetracyano-Bimetallic Assemblies
نویسندگان
چکیده
منابع مشابه
Engineering coordination assemblies of dinuclear CuII complexes.
Hybrid organic-inorganic coordination assemblies are synthesized using modified aminocarboxylic acid ligands as the structure-directing agents. The synthetic approach results in two novel dinuclear copper(II) complexes, K2[CuII(hnida)]2.2H2O (1) and K4[CuII(chnida)]2.4H2O.4MeOH (2) that assemble in the presence of suitable counterions into a densely packed hexagonal array or an open-framework s...
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X-band electron spin resonance (ESR) and electronic spectra of oxalatobridged heterodinuclear Cu-Ni and Cu-Zn complexes, viz., [(PMDT)Cu-Ox-Ni(PMDT)](BPh(4))(2).2CH(3)CN and [(PMDT)Cu-Ox-Zn(PMDT)](BPh(4))(2).2CH(3)CN, where PMDT=pentamethyldiethylenetriamine, Ox=oxalate ion have been described. Complex [(PMDT)Cu-Ox-Ni(PMDT)](BPh(4))(2).2CH(3)CN has been structurally characterized. This complex ...
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ژورنال
عنوان ژورنال: The Open Crystallography Journal
سال: 2011
ISSN: 1874-8465
DOI: 10.2174/1874846501104010002